Approaches for modeling longitudinal dispersion in pore-networks     

R.C. Acharya  S.E.A.T.M. Van der Zee  A. Leijnse 《Advances in water resources》2007

The purpose of this study is to quantify the dispersivity in the longitudinal direction by upscaling pore scale mixing over a network domain and to verify the dispersivity with that obtained through the more rigorous upscaling technique, the Brownian particle tracking model (BPTM). We model a porous medium with a network of pore-units that are comprised of pore bodies and bonds of finite volume. Such a pore-unit is assumed to be a mixing cell with the steady state flow condition for a single fluid. Dispersivity can be obtained by solving the mixing cell model (MCM) for the concentration in each pore-unit and by averaging the concentrations for a large number of pore units (as a function of time and space). A minimal size of network that ascertains an asymptotic value of dispersivity was determined and verified with large size pore networks. This numerically computed dispersivity is compared with the results from the BPTM for the same porous medium and flow conditions. We show that the dispersivity obtained from the MCM is equally reliable for the heterogeneous pore-networks and can be estimated as a function of pore size heterogeneity. For homogeneous networks with the MCM, the iteration time step plays an important role. On the other hand, for networks with the BPTM, the assumption of intra-bond velocity profile affects the results.  相似文献   

基于图像区域特征的细胞识别方法及实现   总被引：5，自引：0，他引：5  

程勇  傅德胜 《南京气象学院学报》2003,26(5):712-716

先提取目标物体的面积、中心矩、圆形度、细长度、核浆比等区域特征。然后采用单原型模式表征方法，利用集群分析技术中最小距离分类器，构造判别函数，并依此作为识别类型的依据。最后，通过对鳞细胞的区域特征进行计算比较，选择出能够较明显地辨别出类别的特征向量，建立判别函数并对结果的可信度进行了讨论。  相似文献   

P–V Equations of State and the relative stabilities of serpentine varieties     

N. Hilairet  I. Daniel  B. Reynard 《Physics and Chemistry of Minerals》2006,33(8-9):629-637

Serpentines are hydrous phyllosilicates which form by hydration of Mg–Fe minerals. The reasons for the occurrence of the structural varieties lizardite and chrysotile, with respect to the variety antigorite, stable at high pressure, are not yet fully elucidated, and their relative stability fields are not quantitatively defined. In order to increase the database of thermodynamic properties of serpentines, the P–V Equations of State (EoS) of lizardite and chrysotile were determined at ambient temperature up to 10 GPa, by in situ synchrotron X-ray diffraction in a diamond-anvil cell. Neither amorphization nor hysteresis was observed during compression and decompression, and no phase transition was resolved in lizardite. In chrysotile, a reversible change in compression mechanism, possibly due to an unresolved phase transition, occurs above 5 GPa. Both varieties exhibit strong anisotropic compression, with the c axis three times more compressible than the others. Fits to ambient temperature Birch–Murnaghan EoS gave for lizardite V ₀=180.92(3) Å³, K ₀ = 71.0(19) GPa and K′ ₀=3.2(6), and for chrysotile up to 5 GPa, V ₀ = 730.57(31) Å³ and K ₀ = 62.8(24) GPa (K′ ₀ fixed to 4). Compared to the structural variety antigorite is stable at high pressure (HP) (Hilairet et al. 2006), the c axis is more compressible in these varieties, whereas the a and b axes are less compressible. These differences are attributed to the less anisotropic distribution of stiff covalent bonds in the corrugated structure of antigorite. The three varieties have almost identical bulk compressibility curves. Thus the compressibility has negligible influence on the relative stability fields of the serpentine varieties. They are dominated by first-order thermodynamic properties, which stabilizes antigorite at high temperature with respect to lizardite, and by out-of-equilibrium phenomena for metastable chrysotile (Evans 2004).  相似文献   

稀土钙钛矿型LaMnO3+λ系列化合物的结构计算与分析     

孙永安  孙立波  王显胜 《世界地质》2005,24(1):102-104

在不同氧分压下合成了LaMnO3 λ、系列化合物，用XRD法进行了结构测定与分析，用化学滴定法测定了Mn^4 含量，由测定结果计算晶胞参数，LaMnO3 λ中系数λ值和La^3 空位率。  相似文献   

晴空日中尺度切变环境场与对流云团发展条件          下载免费PDF全文

雷崇典  师小玲  郑小阳  韩芳琴 《气象》2004,30(1):46-49

重点应用雷达回波资料结合常规气象资料、卫星云图 ,综合分析了 50 0hPa中尺度切变与陕北南部地区对流阵性降水形成、发展条件 ,指出了 50 0hPa不同的中尺度切变与有利的环境合理配置 ,是导致对流云团发展的重要因素 ,不同特征环境风切变配置与对流单体的发展趋势、强度变化、移动和合并息息相关。  相似文献   

An Imaging Photon Counting Intensified CCD for High Speed Photometry     

P. Bergamini  G. Bonelli  A. Paizis  L. Tommasi  M. Uslenghi  R. Falomo  G. Tondello 《Experimental Astronomy》2000,10(4):457-471

The scientific performance evaluation of a photon countingimaging system is presented. The detector is constituted by an ICCD camera with RbTe photocathode(optimized for UV radiation), and dedicated electronics for the acquisition and analysis ofthe events. For each photon event on the CCD, a real-time centroid calculation is performed, inorder to reach spatial resolution down to 25 m FWHM. The system has been tested usingthe 182 cm telescope of the Asiago Observatory.A standard stars field through U Johnson filter,and the Crab pulsar (PSR 0531+21) were observed. From the photometric data, relative magnitudes of the standard stars have been derived, showing a goodlinearity of the detector in the range of flux under consideration, as expected fromprevious laboratory measurements.The pulsar's data have been processed by FFT and epoch foldingtechniques to testthe detector's timing performances in the highest resolutionmode (4.512 ms).These observations show that a space resolved time analysis ofperiodic sources can be performed with 10^-7 s accuracy.  相似文献   

基于GIS的单元簇遗传建模及其在区域矿产预测中的应用     

张振飞  高凤亮  马智民  姬金生 《地球科学与环境学报》2001,23(3):15-19

论述一种GIS支持下的基于"单元簇”概念和遗传建模的多源地学信息综合分析方法及在多目标矿产预测中的应用.在以往矿产定量预测中,根据随机抽样思想进行单元划分,对空间信息利用不够充分.用单元的空间组合("单元簇”)代替单元作为定量类比的基本单位,从而能较好实现地质变量值及其所反映的局部地质空间结构的定量类比;将单元作为GIS区图元,利用GIS空间分析功能实现对单元及单元簇的管理和操作;以已知样品判对率最大为适应值计算准则,用遗传算法建立线性判别函数,可快速有效地实现多目标矿产定位预测.以新疆康古尔塔格地区金矿预测实例说明了其应用效果.  相似文献   

A modeling of the structure and favorable H-docking sites and defects for the high-pressure silica polymorph stishovite     

G. V.?GibbsEmail author  D. F.?Cox  N. L.?Ross 《Physics and Chemistry of Minerals》2004,31(4):232-239

Employing first-principles methods, the docking sites for H were determined and H, Al, and vacancy defects were modeled with an infinite periodic array of super unit cells each consisting of 27 contiguous symmetry nonequivalent unit cells of the crystal structure of stishovite. A geometry optimization of the super-cell structure reproduces the observed bulk structure within the experimental error when P1 translational symmetry was assumed and an array of infinite extent was generated. A mapping of the valence electrons for the structure displays mushroom-shaped isosurfaces on the O atom, one on each side of the plane of the OSi₃ triangle in the nonbonded region. An H atom, placed in a cell near the center of the super cell, was found to dock upon geometry optimization at a distance of 1.69 Å from the O atom with the OH vector oriented nearly perpendicular to the plane of the triangle such that the OH vector makes a angle of 91° with respect to [001]. However, an optimization of a super cell with an Al atom replacing Si and an H atom placed nearby in a centrally located cell resulted in an OH distance of 1.02 Å with the OH vector oriented perpendicular to [001] as observed in infrared studies. The geometry-optimized position of the H atom was found to be in close agreement with that (0.44, 0.12, 0.0) determined in an earlier study of the theoretical electron density distribution. The docking of the H atom at this site was found to be 330 kJ mol^–1 more stable than a docking of the atom just off the shared OO edge of the octahedra as determined for rutile. A geometry optimization of a super cell with a missing Si generated a vacant octahedra that is 20% larger than that of the SiO₆ octahedra. The valence electron density distribution displayed by the two-coordinate O atoms that coordinate the vacant octahedral site is very similar to those displayed by the bent SiOSi angles in coesite. The internal distortions induced by the defect were found to diminish rather rapidly with distance, with the structure annealing to that observed in the bulk crystal to within about three coordination spheres.  相似文献   

粉煤灰湿陷变形的三轴试验和计算     

明经平  赵维炳 《岩土力学》2004,25(Z2):32-38

采用双压力室三轴仪对粉煤灰试样进行了单线法湿陷试验,研究了在静水压力作用以及在不同应力状态和应力水平下粉煤灰湿陷变形的规律,得出了粉煤灰湿陷变形的经验计算公式.提出了计算粉煤灰地基湿陷变形的"全应变曲线"增量有限元法.基于本文的试验结果,对一个粉煤灰地基的湿陷变形进行了有限元计算.  相似文献   

Organochlorines and dioxin-like compounds in green-lipped mussels Perna viridis from Hong Kong mariculture zones     

So MK  Zhang X  Giesy JP  Fung CN  Fong HW  Zheng J  Kramer MJ  Yoo H  Lam PK 《Marine pollution bulletin》2005,51(8-12):677-687

Concentrations of persistent organic pollutants including polychlorinated biphenyls (PCBs), organochlorine (OC) pesticides and dioxin-like compounds were measured in green-lipped mussels, Perna viridis, collected from seven mariculture zones in Hong Kong between September and October in 2002 in order to evaluate the status, spatial distribution and potential sources of pollution in these areas. Concentrations ranged from 300 to 4400 ng/g lipid weight for total OCs and 170–1000 ng/g lipid weight for total PCBs (based on 28 congeners). Relatively smaller DDT concentrations in mussels compared with previous studies suggest reduced discharges of DDTs from nearby regions into Hong Kong waters. Detection of a mixture of HCH isomers in the mussels indicated that Hong Kong waters were predominantly contaminated by technical HCHs rather than lindane. Mussel samples from all sampling locations elicited significant dioxin-like activity in the H4IIE-luc bioassay. The greatest magnitude of dioxin-like response (39 pg TEQ/g wet wt.) was detected in mussels from Ma Wan in the western waters of Hong Kong, which is strongly influenced by the Pearl River discharge. Human health risk assessment was undertaken to evaluate potential risks associated with the consumption of the green-lipped mussels. Risk quotient (RQ) for dioxin-like compounds was greater than unity suggesting that adverse health effects may be associated with high mussel consumption.  相似文献